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No, World of Warcraft addons are specifically blocked from accessing any data not available inside the World of Warcraft directory, as well as communicating with outside software.
I suggest you get a graphics adapter that supports multiple monitors (most cards sold the past two years do) and get another monitor. Neither is very expensive these days. That way you can run WOW on the main screen and still have access to all other applications running on the other. As for me, I use the other one to watch NFL, the latest episodes of my favourite TV-shows or a movie while I grind stuff.
It's really an investment.
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